There is an interesting write up of the St. Pauli Girl spokesmodels here: https://www.alwayswantedonefinds.com/listing/502408046/1980-st-pauli-girl-poster-brunette-hard
The current list of known St. Pauli Girls includes:
1984 Gail Star Smith
1988 Jennifer Fabello
1989 Jennifer Fabello
1990 Felice Schachter
1991 Katie Vogt
1998 Teresa Politi
1999 Jaime Bergman
2000 Angela Little
2001 Neriah Davis
2002 Heather Kozar
2003 Lisa Dergan
2004 Berglind Icey
2005 Stacy Fuson
2006 Brittany Evans
2007 Bobbi Sue Luther
2008 Irina Voronina
2009 Katarina Van Derham
2010 Katarina Van Derham
2011 Jen England
There were other spokesmodels before 1984, but not much is known about them. I'm not sure if card sets were ever made for the other year's spokesmodels.